Synthesis, Characterization and Spectral Studies of a New Azo-Schiff base Ligand Derived from 3,4-diamino benzophenone and its Complexes with Selected Metal Ions
DOI:
https://doi.org/10.6084/rjas.v1i1.251Keywords:
3,4-diamino benzophenone, Azo- Schiff base, Transition metal complexes, Spectral studies.Abstract
The complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pt(II), and Au(III) were prepared from the complexation reaction between the new Azo -Schiff base ligand and Selected Metal Ions. This ligand (3,4-bis(((1E)-1-(2-((2,4-dihydroxy-6- methylphenyl) diazenyl) phenyl) ethylidene) amino) phenyl) (phenyl) methanone) was derived from the condensation reaction of 3,4-diamino benzophenone, 2-amino acetophenone, and 3,5-dihydroxy toluene. The ligand was characterized by C.H.N elemental analysis, Uv-Vis, FT-IR, 1H-NMR, and mass spectra studies, its complexes characterized by C.H.N elemental analysis, Uv-Vis, FT-IR, mass of Ni(II) complex and 1H-NMR of Zn(II) complex, molar conductivity, Atomic absorption, magnetic moment measurements. The results of this studies show the coordination sites for the ligand with the metal ion were to be through oxygen of the hydroxyl group, and the nitrogen of azomethine group and the nitrogen of azo group. The electronic spectral and magnetic measurement data predict octahedral structure of the complexes, except for Pt(II) and Au(III) complexes were suggested a square planar geometry. All complexes show that non electrolytes properties and no conductive species but Pt(II) and Au(III) complexes are electrolyte nature.
References
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[29] A. Mohammed, N. Khaleel and M. aafar, Preparation, Characterization and Biological Study of New Boron Compound and Schiff Base Derived From 2-Aminophenol with Their Cu (II) and Pt (IV) Complexes. IOSR Journal of Applied Chemistry (IOSR-JAC), 2016, 9: 4-11.
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[2] K. Buldurun, N. Turan, A. Savci, and N. Colak, Synthesis, Structural Characterization and biological activities of metal(II) complexes with Schiff bases derived from 5-bromosalicylaldehyde: Ru(II) complexes transfer hydrogenation. Journal of Saudi Chemistry Society, 2019, 23: 205-214.
[3] M. S. Hossain, L. A. Banu, and M. K. E-Zahan, Synthesis, characterization and biological activity studies of mixed ligand complexes with Schiff base and 2,2 ׳-Bipyridine. Appl Sci Res Rev, 2019, 6: 2394-9988.
[4] S. Slassi, A. F. Tailler, G. Larcher, A. Amine, and A. El-Ghayoury, Imidazole and Azo-Based Schiff bases ligands as Highly Active Antifungal and Antioxidant Components: Heteroatom Chemistry, 2019, Article ID 6862170: 8
[5] G. Valarmathy, R. Subbalakshmi, R. Rengathan, and R. Kokila, Synthesis of Schiff base (E)-2-(((3-Hydroxyphenyl)imino)methyl)-6-methoxyphenol Containing N and O Donors and its Metal Complexes: Spectral, Thermal, Redox Behaviour, Fluorescence Quenching, Antimicrobial and Anticancer Studies. Asian .J. chem, 2018, 30: 645-650.
[6] B. S. Wankhede, and A. B. Patil, Studies on Ti(III), Cr(III) and Fe(III), complexes with 1-(1-hydroxynaphthalen-2-yl) ethanone-4-chloro benzoylhdrazone ligand: Synthesis, Physicochemical and Antimicrobial activity. J. Phart, chem& Bio Scien, 2018, 6: 25-33.
[7] A. P. Arumugam, G. Elango, and S. Guhanathan, Synthesis and Characterization of Novel Schiff base Cu(II) Complexes: Antimicrobial and Molecular Docking Studies. J. chem. Envir Scien & Application, 2017, 3: 75-90.
[8] K. Mohammadi, M. Asadi, M. S. Khah, and H. Sepehrpour, Symmetrical and Unsymmetrical Schiff bases Derived from 3,4-Diaminobenzophenone, Synthesis and thermodynamics of five Coordinated Tertiaryphosphine Cobalt(III) Complexes. Croat. Chem. Acta, 2016, 89: 277-284.
[9] F Kunitake, J.Y. Kim, S. Yagi, S. Yamzaki, T. Haraguchi and T. Akitsu, Chiral Recognition of Azo-Schiff Base Ligands, Their Cu(II) Complexes, and Their Docking to Laccase as Mediators. Symmetry, 2019, 11, 666.
[10] N. N. Pesyan, V. Gholsanamloo, M. M. Par, H. Rashidnejad, A. Gharib, and K. Nejati, Synthesis, Characterization and spectroscopic properties of new azo dyes derived from aniline derivatives based on acetylacetone and azo-metal (II) complexes and singular value decomposition (SVD) investigation. Iranian Chemical Communication, 2019, 7:1-19.
[11] B. H. Al-Zaid, M. M. Hasson, and A. H. Ismail, New complexes of chelating Schiff base : Synthesis, spectral investigation, antimicrobial, and thermal behavior studies. J. Appl. Pharm. Scie, 2019, 9: 045-057.
[12] V. Govindaraj, S. Ramanathan, and S. Murgased, Synthesis, Characterization, Antibacterial, Antifungal Screening and Cytotoxic Activity Of Schiff Base Nickel(II) Complexes with Substituted Benzylidine Aminobenzoic Acid. Der Chemica Sinica, 2018, 9: 736-745.
[13] S. H.Mahdi, and L. K. Abdul Karem, Synthesis, Spectral Biochemical Studies of New Complexes of Mixed Ligand Schiff base and Anthranilic Acid. Oriental Journal of Chemistry, 2018, 34: 1565-1572.
[14] B. H. Al-Zaidi, A. H. Ismail, A. N, Naseaf, and W. Khamis, Preparation, Characterization and Biological Activity of New Tridentate Imine- Ligand (H2L) and its Metal Complexes. Asian Journal of Chemistry, 2018, 30: 1157-1164.
[15] K. Mohammadi, M. Asadi, M. Setoodeh. Khah, and H. Sepehrpour, Symmetrical and unsymmetrical Schiff bases Derived from 3,4-Diaminobenzophenone: Synthesis and Thermodynamics of Five Coordinated Teriaryphosphine Cobalt(III) Complexes. Croat Chem Acta, 2016, 89: 277-284.
[16] P. M. Krishna, A. N. Reddy, and K. H. Reddy, Cobalt(II) complex of (3-Amino-5-[(4-ethylbenzaldene)4- methyl-2- phenylcyclopetanone): Synthesis, characterization and photocatalytic studies. International Journal of Chemtech Research, 2019, 12: 171-177.
[17] N. P. yahaya, N. P. Ndahi, L. Bako, M. L. Madugu, A. Zulqiflu, and Y. Mamman, Synthesis and partial Characterization of Two Schiff base ligands with (2 and 4-Nitroaniline) and their Transition Metal (II) (Co and Cu) Complexes. Dutse Journal of pure and Applied Sciences (DUJOPAS), 2018, 4: 584-591.
[18] M. B. Ummathur, P. Sayunderi, and K. Kuutty, Schiff bases of 3-[ 2-(193-Benzothiazol-2-yl] hydrazinyliene] pentane-2,4-dione with aliphatic diamines and their metal. Journal of the Argentine Chemical Society, 2009, 97(2):31-39.
[19] R. M. Okasha , N. E. AL-Shaikh, F. S. Aljohani, A Naqvi, and E H. Ismail , Design of Novel Oligomeric Mixed Ligand Complexes: Preparation, Biological Applications and the First Example of Their Nanosized Scale. International Journal of Molecular Sciences, 2019, 20: 73.
[20] V. H. Baba, K. Venkateswararao, P. Hemamalini, B. Srinivas, and M. Ashok, Binuclear Manganese (II) complexes of anew Schiff base as ligand: Synthesis, Structural characterization, and antibacterial activity. International Journal of Chemtech Research, 2017, 10: 136-143.
[21] N. G. El- Kholy, Synthesis, Spectroscopic characterization, Antimicrobial, Antitumor Properties of new 4-amino-2,3 dimethyl-1-phenyl-3-pyrazolone-5-one(antipyrine)Schiff bases and its transition metal complexes. Journal of American Science, 2017, 13. 2.
[22] N. Raman, R. Jeyamurugan, R. Senthilkumar, B. Rajkapoor, and S. G. Franzblau, In vivo and in vitro evaluation of highly specific thiolate carrier group copper(II) and zinc(II) complexes on Ehrlich ascites carcinoma tumor model. Eur. J. Med Chem, 2010, 45: 5438-51.
[23] J. M. M. Al-Zinkee, and A. J. Jarad, Synthesis, Spectral Studies and Microbial Evaluation of Azo Due Lgand Complexes with Some Transition Metals. J. Pharm. Sci & Res, 2019, 11. 98-103.
[24] S. H. Kadhim, I. Q. Abd-Alla, and T. J. Hashim, Synthesis and Characterization Study of Co(II), Ni(II), and Cu(II) Complexes of New Schiff base Derived from 4-Amino Antipyrine. International Journal of Chemical Sciences, 2017, 15: 107.
[25] M. Mohamad, Some transition metal complexes with new Schiff base ligand hexadentate. Acta Chimica. Pharm. Indica, 2013, 3. 140-148.
[26] R. Ferjani, M. Ahmad, F. Harum, and B. Bulgasem, Synthesis, Characterization and antibacterial activity of Schiff base derived from 4-Dimethyl amino benzaldehyde with some amino Acids and 4-amino antipyrine toward Cu(II), (Ni(II), Co(II), Cd (II) and Mn (II) Ions. Journal of Applied chemistry (IOSR-JAC), 2017, 10 : 6 – 13.
[27] R. K. Al-Shemary, A. M. Al-Khazraji, and A. N. Niseaf, Preparation, Spectroscopic study of Schiff base ligand complexes with some metal ions and Evaluation of antibacterial activity. The Pharma Innovation Journal, 2016, 5: 81-86.
[28] E. Canpolat, A. Aglamis, H. Sahal, and M. Kaya, Some Transition Metal Complexes of NO Type Schiff Base. Preparation and Characterization: Science Journal (CSJ), 2016, 37. 1300-1949.
[29] A. Mohammed, N. Khaleel and M. aafar, Preparation, Characterization and Biological Study of New Boron Compound and Schiff Base Derived From 2-Aminophenol with Their Cu (II) and Pt (IV) Complexes. IOSR Journal of Applied Chemistry (IOSR-JAC), 2016, 9: 4-11.
[30] B. M. H. Ameen, and H. A. Mohamad, Synthesis and Characterization of Pd(II) And Pt(II) Complexes with Bis [Hg (2-Apt)] Compound. Kirkuk University Journal /Scientific Studies (KUJSS), 2018, 13.
[31] P. Deshmuck, P.Soni, A.koriya, A. Halve and R. Dixit, 4-Amino antipyrine: A significant tool for the synthesis of Biologically active Schiff base and metal complexes. Int. J. Pharm. Sci, Rev, 2015, 34: 162 – 170.
[32] A. Bergamo, and G. Sava, Linking the future of anticancer metal-complexes to the therapy of tumour metastases. Chemical Society Reviews, 2015, 44: 8818-8835.
[33] A. P. Arumugam, S. Guhanathan, and G. Elango, Co(II), Ni(II) and Cu(II) Complexes with Schiff base Ligand: Synthesis, Characterization, Antimicrobial Studies and Molecular Doching Studies. SOJ Materials Science & Engineering, 2017, 5. 142.
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How to Cite
Synthesis, Characterization and Spectral Studies of a New Azo-Schiff base Ligand Derived from 3,4-diamino benzophenone and its Complexes with Selected Metal Ions. (2020). Research Journal in Advanced Sciences, 1(1). https://doi.org/10.6084/rjas.v1i1.251
